Thanks very much to everyone for your opinions and advice.
I read all of your replies, and was torn between wanting to try again to get as much syrup into them as fast as I can, and just accepting fate and going with the emergency sugar feed. Being a beginner without a mentor, I decided to try all three things - paint cans, baggies and dry sugar on newspaper! I have 10 hives, so was able to try them all in various combinations.
Here's what I found.....
When I made bigger holes in the lids, most of the paint tins placed directly over the cluster were drained almost overnight. The cans set to one side of the cluster were generally not touched. Reasons for this are now fairly obvious to me given what you all told me. However I was worried that the holes in the lid were too big and that perhaps the syrup had just leaked all over the bees. I tested this theory out and refilled an empty can and set it upside down outside for two days. No syrup was lost, so it seems that the bees were draining them when they were over the cluster.
The baggies were a big success too, with three out of four drained. One was untouched, I suspect because I didn't puncture the bag properly. Most of the bees were also taking the sugar too, an indication for me that times are very tough for my bees right now.
So in retrospect, it seems that the reason they were not taking the syrup initially was that I made the holes in the lid too small, and the syrup crystalised, covering the holes. As temperatures continue to fall down here, I'm going to switch from the tins to the baggies, and will keep using them until they stop taking them. I'll keep the dry sugar up to them all Winter.
Thanks again for your help, apologies for the long post, but I learn most when people post updates to problems they've received advice on and I want to try and do the same.
Best regards,
Koala John.